Doctoral Candidates
Graduate Student, Scientific Aide
Research Interests
Organic Magnets
Matrix Isolation Spectroscopy
Publications
Articles based on doctoral reseach:
[1]
Electronic Effects on Atom Tunneling: Conformational Isomerization of Monomeric Para-Substituted Benzoic Acid Derivatives.
Shadi Amiri, Hans P. Reisenauer, Peter R. Schreiner*
J. Am. Chem. Soc.
2010
, 132
, 15902–15904
.
Download
[2] Non-Kekulé N-Substituted m-Phenylenes: N-Centered Diradicals versus Zwitterions. Shadi Amiri, Peter R. Schreiner* J. Phys. Chem. A 2009 , 113 , 11750–11757. Download
[3]
Understanding the Torquoselectivity in 8π-Electrocyclic Cascade Reactions: Synthesis of Fenestradienes versus Cyclooctatrienes.
Catherine Hulot, Shadi Amiri,
Gaëlle Blond, Peter R. Schreiner,* and Jean Suffert*
J. Am. Chem. Soc.
2009
, 113
, 13387–13398.
Download
[4] 3,5,7,9-Substituted Hexaazaacridines: Toward Structures with Nearly Degenerate Singlet-Triplet Energy Separations. Peter Langer,* Shadi Amiri, Anja Bodtke, Nehad Saleh, Klaus Weisz, Halmar Görls, and Peter R. Schreiner* J. Org. Chem. 2008 , 73 , 5048–5063. Download
Articles based on M. Sc. research:
[1] High-Coordinated Lanthanum(III) Complexes with New Mono- and Bidentate Phosphoryl Donors; Spectroscopic and Structural Aspects. Gholivand, K.; Mahzouni, H. R.; Pourayoubi, M.; Amiri, S. Inorg. Chim. Acta 2010 , 363 , 2318–2324. Download
[2] Structural diversity in phosphoramidate's chemistry: Syntheses, spectroscopic and X-ray crystallography studies. Gholivand, K.; Shariatinia, Z.; Mashhadi, S. M.; Daeepour, F.; Farshidnasab, N.; Mahzouni, H. R.; Taheri, N.; Amiri, S.; Ansar, S. Polyhedron 2009 , 28 , 307–321. Download
[3] Synthesis, spectroscopic study, X-ray crystallography and ab initio calculations of the two new phosphoramidates: C 6 H 5 OP(O)(NHC 6 H 11 ) 2 and [N(CH 3 )(C 6 H 11 )]P(O)(2-C 5 H 4 N-NH) 2 . Gholivand, K.; Della Vedova, C. O.; Erben, M. F.; Mahzouni, H. R.; Shariatinia, Z.; Amiri, S. J. Mol. Struct. 2008 , 874 , 178–186. Download
[4] Phosphorus heterocycles: synthesis, spectroscopic study and X-ray crystallography of some new diazaphosphorinanes. Gholivand, K.; Shariatinia, Z.; Mahzouni, H. R.; Amiri, S. Struct. Chem. 2007 , 18 , 653–660. Download
Graduate Student, Research Associate
Field of Work:
Former graduate Student, Research Associate, Coordinator Liebig College
Field of Work
Postfunctionalization of Rhodium(II) Complexes
Postfunctionalization of Sn/S Cluster
Site-Selective Nitrenoid Insertions
Now:
AllessaProduktion GmbH
Alt-Fechenheim 34
D-60386 Frankfurt am Main
Photo: Katrina Friese
Publications
Diamondoid Amino Acid ‐ Based Peptide Kinase A Inhibitor Analogues. Janis Müller, Romina A. Kirschner, Jan-Philipp Berndt , Tobias Wulsdorf, Alexander Metz, Radim Hrdina, Peter R. Schreiner, Armin Geyer, Gerhard Klebe, Chem. Med. Chem. 2019 , DOI: 10.1002/cmdc.201800779 .
Site-selective nitrenoid insertions utilizing postfunctionalized bifunctional rhodium(II) catalysts. Jan-Philipp Berndt , Yevhenii Radchenko, J. Becker, Christian Logemann, Dhaka R. Bhandari, Radim Hrdina, Peter R. Schreiner, Chem. Sci. 2019 , 10 , 3324-3329. DOI: 10.1039/C8SC05733H
Azido-Adamantyl Tin Sulfide Clusters for Bioconjugation. Jan-Philipp Berndt, Annikka Engel, Radim Hrdina, Stefanie Dehnen, Peter R. Schreiner, Organometallics 2019 , 38 , 329-335. DOI : 10.1021/acs.organomet.8b00734
Selective Phthalimido-N-oxyl (PINO)-Catalyzed C–H Cyanation of Adamantane Derivatives. Jan-Philipp Berndt, Frederik Erb, Lukas Ochmann, Jaqueline. Beppler, Peter R. Schreiner, Synlett 2019 , 30 , 493-498. DOI: 10.1055/s-0037-1610403
Peptide-Functionalized Sn/S Clusters.
Niklas Rinn,
Jan-Philipp Berndt
, Annikka Kreher, Natalie Brüll, Radim Hrdina, Matthias Reinmuth, Peter R. Schreiner and Stefanie Dehnen.
Organometallics
2016
,
35
, 3215–3220.
DOI: 10.1021/acs.organomet.6b00561
Intramolecular C-H amination provides direct access to 1,2-disubstituted diamondoids.
Radim Hrdina, Fabian Metz, Marta Larrosa,
Jan-Philipp Berndt,
Yevheniia Zhygadlo, Sabine Becker, Jonathan Becker.
Eur. J. Org. Chem.
2015,
DOI: 10.1002/ejoc.201500691
Research Associate
Field of Work
Reactive Intermediates , Computational Chemistry , Tunneling Studies
Photo: Katrina Friese
Research Associate
Field of Work
Publications
Mild Aliphatic and Benzylic Hydrocarbon C–H Bond Chlorination Using Trichloroisocyanuric Acid (TCCA)
Sascha H. Combe, Abolfazl Hosseini, Alejandro Parra, and Peter R. Schreiner
J. Org. Chem. 2017 , 82 , 2407-2413. DOI: 10.1021/acs.joc.6b02829
Catalytic Halogen Bond Activation in the Benzylic C–H Bond Iodination with Iodohydantoins
Sascha H. Combe, Abolfazl Hosseini, Lijuan Song, Heike Hausmann, and Peter R. Schreiner
Org. Lett. 2017 , 19 , 6156-6159. DOI: 10.1021/acs.orglett.7b03034
Research Associate, FCI Fellow
Field of Work / Research Interests
Reactive Intermediates (Matrix Isolation Spectroscopy), Quantum Mechanical Tunneling and Tunneling Computations, Computational Chemistry
Currently Postdoctoral Research Fellow at
Ruhr-University Bochum (RUB), Lehrstuhl für Organische Chemie II
Photo: Katrina Friese
Publications
Competitive Nitrogen versus Carbon Tunneling. C. M. Nunes, A. K. Eckhardt, I. Reva, R. Fausto and P. R. Schreiner J. Am. Chem. Soc . 2019 , 141 , 14340-14348, doi: 10.1021/jacs.9b06869
Formation of Glyoxylic Acid in Interstellar Ices: A Key Entry Point for Prebiotic Chemistry. A. K. Eckhardt, A. Bergantini, S. K. Singh, P. R. Schreiner and R. I. Kaiser Angew. Chem. Int. Ed. 2019, 58 , 5663-5667, doi: 10.1002/anie.201901059
Caged Nitric Oxide-Thiyl Radical Pairs. Z. Wu, C. Chen, J. Liu, Y. Lu, J. Xu, X. Liu, G. Cui, T. Trabelsi, J. S. Francisco, A. Mardyukov, A. K. Eckhardt, P. R. Schreiner and X. Zeng J. Am. Chem. Soc . 2019 , 141 , 3361-3365, doi: 10.1021/jacs.8b12746
Conformer-specific [1,2] H -tunnelling in captodatively-stabilized cyanohydroxycarbene (NC–C̈–OH). A. K. Eckhardt, F. R. Erb and P. R. Schreiner
Chem. Sci. 2019 , 10 , 802-808, DOI: 10.1039/C8SC03720E
1,3-Dioxolane-4-ol Hemiacetal Stores Formaldehyde and Glycolaldehyde in the Gas-Phase. A. K. Eckhardt, R. C. Wende and P. R. Schreiner
J. Am. Chem. Soc. 2018 , 140, 12333–12336, DOI: 10.1021/jacs.8b07480
Gas-phase sugar formation using hydroxymethylene as the reactive formaldehyde isomer. A. K. Eckhardt, M. M. Linden, R. C. Wende, B. Bernhardt and P. R. Schreiner
Nature Chem. 2018 , 10 , 1141–1147, DOI:10.1038/s41557-018-0128-2
Phenylsulfinyl Radical: Gas Phase Generation, Photoisomerization, and Oxidation. J. Xu, Z. Wu, H. Wan, G. Deng, B. Lu, A. K. Eckhardt, P. R. Schreiner, T. Trabelsi, J. S. Francisco and X. Zeng
J. Am. Chem. Soc. 2018 , 140 , 9972-9978, DOI:10.1021/jacs.8b05055
Spectroscopic Evidence for Aminomethylene (H−C̈−NH 2 ) – The Simplest Amino Carbene. A. K. Eckhardt and P. R. Schreiner Angew. Chem. Int. Ed. 2018, 57 , 5248-5252, doi:10.1002/anie.201800679 .
The near-UV absorber OSSO and its Isomers. Z. Wu, H. Wan, J. Xu, B. Lu, Y. Lu, A. K. Eckhardt, P. R. Schreiner, C. Xie, H. Guo and X. Zeng Chem. Commun. 2018, 54 , 4517-4520, doi:10.1039/c8cc00999f .
Capture of SO 3 Isomers in the Oxidation of Sulfur Monoxide with Molecular Oxygen. Z. Wu, B. Lu, R. Feng, J. Xu, Y. Lu, H. Wan, A. K. Eckhardt, P. R. Schreiner, C. Xie, H. Guo and X. Zeng Chem. Commun. 2018, 54 , 1690-1693, doi:10.1039/c7cc09389f .
Heavy Atom Secondary Kinetic Isotope Effect on H-Tunneling. A. K. Eckhardt, D. Gerbig and P. R. Schreiner J. Phys. Chem. A 2018, 122 , 1488-1495, doi:10.1021/acs.jpca.7b12118 .
The Trifluoromethyl Sulfinyl and Oxathiyl Radicals. Z. Wu, J. Xu, G. Deng, X. Chu, L. Sokolenko, T. Trabelsi, J. S. Francisco, A. K. Eckhardt, P. R. Schreiner and X. Zeng Chem. Eur. J. 2018, 24 , 1505-1508, doi:10.1002/chem.201705142 .
The 1943 K Emission Spectrum of H 2 16 O Between 6600 and 7050 cm −1 . E. Czinki, T. Furtenbacher, A. G. Császár, A. K. Eckhardt and G. C. Mellau J. Quant. Spectrosc. Radiat. Transfer 2018, 206 , 46-54, doi:10.1016/j.jqsrt.2017.10.028 .
Graduate Student, Research Associate
Field of Work:
Metal-free Functionalization of Unactivated C(sp 3 )–H Bonds, Photochemistry, Organic Electrosynthesis, Organocatalysis
Photo: Katrina Friese
Graduate Student, former Research Associate
Field of Work:
Organocatalysis , Dispersion Interactions in CBS-Reductions, Lewis Acid Enhancement by Thioureas
Photo: Katrina Friese
Postdoc, Research Associate
Justus-Liebig Universität Gießen
Heinrich-Buff-Ring 17
35392 Gießen
Areas of research:
Studies:
10/2001 – 05/2007
Intermediate Examination: 9/2003(chemistry) 3/2004 (french)
1st. state examination: 5/2007
Final Thesis: 11/2005 - 2/2006
Title:
„Synthese und Charakterisierung von Dithiolthionen als chemopräventive Wirkstoffe in der Krebsprophylaxe“
(rewarded for the final thesis 6/2007)
Ph.D Studies:
Under the supervision of Prof Dr. P. R. Schreiner
Since 11/2007
Since 01/2009 Graduiertenstipendium (Justus-Liebig University Giessen)
Title: Heuristic Chemistry
Promotion:
Under the supervision of Prof Dr. P. R. Schreiner
11/2007 – 6/2011
01/2009 – 6/2011 Graduiertenstipendium (Justus-Liebig University Giessen)
Title: “Heuristic Chemistry”
Teaching experience:
2/2003 – 8/2006 Graduate assistant in the Institute for Didactics in Chemistry at the JLU
Since 11/2007: Assistant in the laboratory courses and seminars for organic chemistry at the JLU
2002 – 2006 Coach at Mind Unlimited (company providing courses in learning methodology and science camps for students)
List of Publications:
1.
N. Graulich, H. Hopf, P. R. Schreiner, “Heuristic Thinking Makes A Chemist Smart”,
Chem. Soc. Rev.
2010
,
39
(5), 1503–1512.
2.
N. Graulich, H. Hopf, P. R. Schreiner, “Heuristic Chemistry – Addition Reactions”,
Chem. Eur. J.
2010
,
17
(1), 30-40.
3.
N. Graulich, “The Cope Rearrangement – The First Born of a Great Family”,
WIREs – Computational
Molecular Science
2011
,
1
(2), 172-190.
4.
N. Graulich, P. R. Schreiner, “Struktur-Eigenschafts-Beziehungen in der Organischen Chemie – Über die
Entwicklung neuer Lehrkonzepte”,
CHEMKON
2011
,
in press
.
5.
N. Graulich, H. Hopf, P. R. Schreiner, “Heuristic Chemistry – Elimination Reactions”,
Chem. Asian J.
2011
,
accepted for publication
.
Conference Proceedings:
1.
N. Graulich, R. Tiemann, P. R. Schreiner, “Heuristic Chemistry – A Qualitative Case Study”, in D.
Höttecke (Ed.), Naturwissenschaftliche Bildung als Beitrag zur Gestaltung partizipativer Demokratie.
GDCP-Jahrestagung in Potsdam 2010, Lit-Verlag: Berlin,
2010
, p. 408-410.
2.
N. Graulich, H. Hopf, P. R. Schreiner, “Heuristic Chemistry”, in D. Höttecke (Ed.), Entwicklung
naturwissenschaftlichen Denkens zwischen Phänomen und Systematik. GDCP-Jahrestagung in
Dresden 2009, Lit-Verlag: Berlin,
2009
, p. 449-451.
Field of Work:
Metallization of diamondoids for Chemical Vapor Deposition
Dr. Kira Hof
Graduate Student, Research Associate
Publications:
A. T. Messmer, K. M. Lippert, S. Steinwand, E.-B. W. Lerch, K. Hof, D. Ley, D. Gerbig, H. Hausmann, P. R. Schreiner, J. Bredenbeck, " Two-dimensional Infrared Spectroscopy Reveals Structural Details of an Evans Auxiliary and its SnCl 4 Complex", Chem. Eur. J. 2012 , 18 , 14989—14995.
K. M. Lippert, K. Hof, D. Gerbig, D. Ley, H. Hausmann, S. Guenther, P. R. Schreiner, " Hydrogen Bonding Thiourea Organocatalysts: The Privileged 3,5-Bis(trifluoromethyl)phenyl Group", Eur. J. Org. Chem. 2012 , 5919—5927.
K. Hof, K. M. Lippert, P. R. Schreiner, “Hydrogen-Bonding Catalysts: (Thio)urea Catalysis” in Science of Synthesis Asymmetric Organocatalysis 2: Brønsted Base and Acid Catalysts, And Additional Topics (Ed.: K. Maruoka), Thieme, Stuttgart, 2011 , pp. 297–412.
P. Rooshenas, K. Hof, P. R. Schreiner, C. M. Williams, “1,2,4-Triazine vs. 1,3- and 1,4-Oxazinones in Normal- and Inverse-Electron-Demand Hetero-Diels–Alder Reactions: Establishing a Status Quo by Computational Analysis", Eur. J. Org. Chem. 2011 , 983–992.
Graduate Student, Research Associate
Field of Work:
Organocatalysis
Quinine Derivatives
(Thio)urea Organocatalyst Equilibrium Acidities in DMSO
No working at
C-Capture Ltd., Leeds, UK
Former Position: Graduate Student, Research Associate
|
|
|---|
Research Associate
Field of Work
Reactive Intermediates , Computational Chemistry and Synthesis
Publications
Synthesis of enantioenriched phtalide and isoindolinone derivatives from 2-formylbenzoic acid. D. Niedek, S. M. M. Schuler, C. Eschmann, R. C. Wende, A. Seitz, F. Keul , P. R. Schreiner, Synthesis , 2017 , 49 , 371-382.
Preparation and characterization of phenyl phosphine diselenide – the monomeric form of Woollin´s reagent. A. Mardyukov, F. Keul , P. R. Schreiner, Eur. J. Org. Chem. , 2019 , 2-3 , 387-390.
Spectroscopic identification of the phenyltelluryl radical and its reactivity with molecular oxygen. F. Keul , A. Mardyukov, P. R. Schreiner, Phys. Chem. Chem. Phys. , 2019 , 21, 25797-25801.
Generation and spectroscopic identification of the thiuram radical (CH 3 ) 2 NCS 2 . A. Mardyukov, F. Keul , P. R. Schreiner, J. Phys. Chem. A , 2019 , 123 , 4937-4941.
Preparation and spectroscopic identification of methyl-Se-nitroselenol. L. Song, F. Keul , A. Mardyukov, Chem. Commun. , 2019 , 55 , 9943-9946.
Isolation and characterization of the free phenylphosphinidene chalgonides C6H5P=O and C6H5P=S, the phosphorus analogues of nitrosobenzene and thionitrosobenzene. A. Mardyukov, F. Keul , P. R. Schreiner, Angew. Chem. Int. Ed. , 2020 , 59 , 12445-12449.
Preparation and characterization of the enol of acetamide: 1-aminoethenol, a high-energy prebiotic molecule. A. Mardyukov, F. Keul , P. R. Schreiner, Chem. Sci. , 2020 , 11, 12358-12363.
1,1,2-Ethentriol: The enol of glycolic acid, a high-energy prebiotic molecule. A. Mardyukov, F. Keul , P. R. Schreiner, Angew. Chem. Int. Ed. , 2021 , 60 , 15313-15316.
Graduate Student, Research Associate
Graduate Student
|
|
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Field of Work: Unsaturated Nanodiamonds: Synthesis and functionalization of coupled diamondoids as direct route to the nano building blocks |
Research Associate
|
Arbeitsgebiete:
Projektplanung und -durchführung, Forschung & Entwicklung: Praktische/experimentelle/theoretische Organische Chemie, Organische Synthesechemie und instrumentelle Analytik; Organokatalyse (Katalyseforschung), insbesondere wasserstoffbrücken-bildende (Thio)Harnstoffderivate: Methodenoptimierung für die Anwendung in der Organischen Synthese; Literaturrecherche, Autor wissenschaftlicher Publikationen. Dissertation : Originaltitel der Arbeit: “Hydrogen-Bonding (Thio)urea Organocatalysts in Organic Synthesis: State of the Art and Practical Methods for Acetalization, Tetrahydropyranylation, and Cooperative Epoxide Alcoholysis” Free download of this PhD thesis (pdf) from the Electronic Library. Deutscher Titel: „ Wasserstoffbrücken-bildende (Thio)Harnstoff-Organokatalysatoren in der Organischen Synthese: Stand der Forschung und praktische Methoden zur Acetalisierung, Tetrahydropyranylierung und Kooperativen Epoxidalkoholyse“ Bewertung mit “summa cum laude” (ausgezeichnet); Disputation: 08.10.2009 |
Publikationsliste (List of Publications)
Buchbeitrag (Book Contribution)
Journalpublikationen (Journal Publications)
[4] T. Weil, Mike Kotke , C. M. Kleiner, P. R. Schreiner, “Cooperative BrØnsted Acid-Type Organocatalysis: Alcoholysis of Styrene Oxides”, Org. Lett. 2008 , 10, 1513–1516. Download
Graduate Student, Linux System Administration and Maintenance
Research Associate, JCF Delegate for the International Young Chemist Network (IYCN)
Now:
AllessaProduktion GmbH
Alt-Fechenheim 34
D-60386 Frankfurt am Main
Photo: Katrina Friese
Research Associate
Field of Work
Morita-Baylis-Hillman reaction
Phase transfer catalysis
Book Review of Asymmetric Phase Transfer Catalysis
Publications:
Structure analysis of substrate catalyst complexes in mixtures with ultrafast two-dimensional infrared spectroscopy. A. T. Messmer, K. M. Lippert, P. R. Schreiner, J. Bredenbeck Phys. Chem. Chem. Phys. 2013 , 15 , 1509–1517.
Ultrafast Two-Dimensional Infrared Spectroscopy Resolves the Conformational Change of an Evans Auxiliary Induced by Mg(ClO4)2. A. T. Messmer, S. Steinwand, K. M. Lippert, P. R. Schreiner, J. Bredenbeck, J. Org. Chem. 2012 , 77 , 11091–11095.
Hydrogen Bonding Thiourea Organocatalysts: The Privileged 3,5-Bis(trifluoromethyl)phenyl Group
K. M. Lippert, K. Hof, D. Gerbig, D. Ley, H. Hausmann, S. Guenther, P. R. Schreiner
Eur. J. Org. Chem.
2012
, 5919—5927.
Two-dimensional Infrared Spectroscopy Reveals Structural Details of an Evans Auxiliary and its SnCl 4 Complex A. T. Messmer, K. M. Lippert, S. Steinwand, E.-B. W. Lerch, K. Hof, D. Ley, D. Gerbig, H. Hausmann, P. R. Schreiner, J. Bredenbeck Chem. Eur. J. 2012 , 18 , 14989—14995.
(Thio)urea Organocatalyst Equilibrium Acidities in DMSO G. Jakab, C. Tancon, Z. Zhang, K. M. Lippert, P. R. Schreiner P. R. Org. Lett. 2012 , 14 , 1724—1727.
Hydrogen-Bonding Catalysts: (Thio)urea Catalysis K. Hof, K. M. Lippert, P. R. Schreiner, Science of Synthesis Asymmetric Organocatalysis 2: Brønsted Base and Acid Catalysts, And Additional Topics (Ed.: K. Maruoka), Thieme, Stuttgart, 2011 , pp. 297—412.
Cooperative Thiourea–Brønsted Acid Organocatalysis: Enantioselective Cyanosilylation of Aldehydes with TMSCN Z. Zhang, K. M. Lippert, H. Hausmann, M. Kotke, P. R. Schreiner J. Org. Chem. 2011 , 76 , 9764—9776.
Silicon–(Thio)urea Lewis Acid Catalysis R. Hrdina, C. E. Müller, R. C. Wende, K. M. Lippert, M. Benassi, B. Spengler, P. R. Schreiner J. Am. Chem. Soc. 2011, 133 , 7624—7627.
Graduate Student, Research Associate
Field of Work
„Substitutionsmaterialien für nachhaltige Energietechnologien“
„Substitute Materials for Sustainable Energy Technologies“
Now working at:
milch & zucker
Talent Acquisition & Talent Management Company AG
Graduate Student, Scientific Aide, Linux-Cluster Designer
Field of Work:
Mechanistische Untersuchungen zur 4-Dimethylaminopyridin (DMAP) - katalysierten Acetylierung von Alkoholen
Dipl. Chem. V. Lutz, Dr. J. Glatthaar und Prof. Dr. P. Schreiner
Abstrakt. N
-Acetyl-Pyridiniumacetat (
1,
X = CH
3
CO
2
-
, Abbildung 1) wird in der DMAP (
2
) – katalysierten Acetylierung von Aminen und Alkoholen als katalytisch aktive Spezies diskutiert.
[1]
Wir konnten anhand analoger Salze wie
3a
und
3b
sowie theoretischer Betrachtungen deren Stabilität auf die Nucleophilie des entsprechenden Anions zurückführen, wie auch auf dessen Fähigkeit, das Ionenpaar durch Wasserstoffbrückenbindungen im Kristallgitter zu stabilisieren.
[2]
Spektroskopische Untersuchungen ergaben zudem, dass die Konzentration von
1
in Dichlormethan mit < 1% beträchtlich geringer ist als bisher angenommen.
[3]
Die dennoch hohe katalytische Aktivität muss daher in direktem Zusammenhang mit der Fähigkeit des Anions stehen, die nachfolgende Reaktion mit Alkoholen wiederum durch Wasserstoffbrückenbindungen zu assistieren.
[1] W. Steglich, G. Hoefle, Angew. Chem. Int. Ed. Engl. 1969 , 8 , 981; L. M. Litvinenko, A. I. Kirichenko, Dokl. Akad. Nauk SSSR 1967 , 176 , 197-100.
[2] V. Lutz, J. Glatthaar, C. Wuertele, M. Serafin, P. R. Schreiner, Chem. Eur. J. 2009 , in press.
[3] G. Höfle, W. Steglich, H. Vorbrüggen, Angew. Chem. Int. Ed. 1978 , 17 , 569-583.
Now:
Allessa Produktion GmbH
Alt-Fechenheim 34
D-60386 Frankfurt am Main
Publications:
- Diamondoid Phosphines - Selective Phosphorylation of Nanodiamonds. Functionalized Nanodiamonds, part 26. Hartmut Schwertfeger, Mareike M. Machuy, Christian Würtele, Jeremy E. P. Dahl, Robert M. K. Carlson and Peter R. Schreiner* Adv. Synth. Catal. 2010 , 352 , 609-615.
- 2,6-Bis(phenylethynyl)biphenyls and Their Cyclization to Pyrenes. M. M. Machuy, C. Würtele, P. R. Schreiner, Synthesis , 2012 , 44 , 1405-1409.
Graduate Student, Research Associate
|
|
Research Associate
Field of Work
Now working at:
Reddy Holding GmbH / betapharm Arzneimittel GmbH
86156 Augsburg
www.drreddys.com / www.betapharm.com
Photo: Katrina Friese
Postdoc, Research Associate
Research areas:
Organocatalysis, Kinetic Resolutions and Desymmetrizations of Alcohols, Peptide Based Catalysts Incorporating Non-Natural γ -Amino Adamantane Carboxylic Acids, Automated Peptide Synthesis, Design and Development of Novel Multifunctional Catalysts, Organocatalytic Tandem Reactions.
Studies:
Wintersemester 2001 – Summersemester 2006; Intermediate Exam (Vordiplom): 10/2003; Final Exam (Diplom): January/February 2006; Diploma Thesis: 03/2006 – 09/2006; Title: Novel Peptides Based on Adamantyl Carboxylic Acids; Group: Prof. Schreiner, Justus-Liebig Universitity, Giessen
Promotion:
10/2006-3/2011 Titel: Nucleophilic Oligopeptide Organocatalysis: Acylation, Oxidation, and Multicatalysis; Group: Prof. Schreiner, Justus-Liebig Universitity, Giessen
List of Publications: Link
1) Enantioselective Kinetic Resolution of trans-Cycloalkane-1,2-diols − Enantioselektive Kinetische Racematspaltung von trans-Cycloalkan-1,2-diolen: Christian E. Müller, Lukas Wanka, Kevin Jewell, Peter R. Schreiner, Angew. Chem. Int. Ed. 2008 , 47 , 6180-6183; Angew. Chem. 2008 , 47 , 6275-6278.
2) One-Pot Desymmetrization of meso-1,2-Hydrocarbon Diols through Acylation and Oxidation: Christian E. Müller, Daniela Zell, Peter R. Schreiner, Chem.-Eur. J. 2009 , 15 , 9647-9650.
3 ) Kinetic Resolution of trans-Cycloalkane-1,2-diols via Steglich Esterification: Radim Hrdina, Christian E. Müller, P. R. Schreiner, Chem. Commun. 2010 , 46, 2689-2690.
Highlight: Enantioselective Steglich Esterification for the Resolution of 1,2-Diols:
Benjamin List, Olga Lifchits,
Synfacts
2010
, 594.
4) Organocatalytic Enantioselective Acyl Transfer onto Racemic as well as meso Alcohols, Amines, and Thiols − Organokatalytischer, Enantioselektiver Acyltransfer auf Racemische sowie meso-Alkohole, -Amine und -Thiole: Christian E. Müller, Peter R. Schreiner, Angew. Chem. Int. Ed. 2011 , 50 , 6012–6042; Angew. Chem. 2011 , 123 , 6136-6167.
5) Silicon-(Thio)urea Lewis Acid Catalysis: Radim Hrdina, Christian E. Müller, Raffael C. Wende, Katharina M. Lippert, Peter R. Schreiner, J. Am. Chem. Soc. 2011 , 133 , 7624–7627.
6) A Multicatalyst System for the One-Pot Desymmetrization / Oxidation of meso-1,2-Alkane Diols: Christian E. Müller, Radim Hrdina, Raffael C. Wende, Peter R. Schreiner, Chem.-Eur. J. 2011 , 17 , 6309–6314.
Research Associate
(esp.) Triplet Carbenes
2006 - present doctoral research
Scientific Awards and Scholarships:
2003 - 2004 das Gießener Liebig-Stipendium (best chemistry student)
2003 - fellowship of the Studienstiftung des Deutschen Volkes
2006 - predoctoral scholarship of the Studienstiftung des Deutschen Volkes
2006 - predoctoral grant of the VCI
Former graduate Student, Research Associate
Field of Work
Peptide catalyzed Baeyer-Villiger reactions, Design of new peptide based catalysts, Photoswitchable Catalysis, Site-Selective Catalysis
Now:
Allessa GmbH
D-60386 Frankfurt am Main
Photo: Katrina Friese
Research Associate
Field of Work
Nanodiamonds (Diamondoids) , Functionalization of Diamondoids, Organohybrids, Diamondoids in Catalysis
Now:
Process chemist Scale-Up
CMBlu Energy AG
Industriestraße 19
63755 Alzenau
Graduate Student, Research Associate
Field of Work/Research Interest
Organocatalysis, Peroxide chemistry, Aromatic and alkene oxidations, Asymmetric synthesis
Photo: Katrina Friese
Publications
- Afsaneh Pilevar, Abolfazl Hosseini, Marina Šekutor, Heike Hausmann, Jonathan Becker, Kevin Turke and Peter R. Schreiner “Tuning the Reactivity of Peroxo-Anhydrides for Aromatic C–H Bond Oxidation” J. Org. Chem. 2018 , 83 , 10070–10079.
- Abolfazl Hosseini, Afsaneh Pilevar, Eimear Hogan and Peter R. Schreiner “Calcium Carbide Catalytically Activated with Tetra- n -butyl Ammonium Fluoride for Sonogashira Cross-Coupling Reactions” Org. Biomol. Chem. 2017 , 15 , 6800–6807.
Now Head of Laboratory at
Fabrik chemischer Präparate von Dr. Richard Sthamer GmbH & Co. KG, Hamburg
Graduate Student, former Research Associate
Field of Work
Photo: Katrina Friese
Publications
Trifluoromethylhydroxycarbene: Conformer-specific hydrogen-atom tunneling.
Artur Mardyukov, Henrik Quanz, and Peter R. Schreiner
Nature Chem.
2017
,
9
, 71–77.
DOI: 10.1038/nchem.2609
Polytriangulane.
Wesley D. Allen, Henrik Quanz, and Peter R. Schreiner
J. Chem. Theory Comput.
2016
,
12
, 4707–4716.
DOI: 10.1021/acs.jctc.6b00669
Polytwistane.
Shiblee Barua, Henrik Quanz, Martin Olbrich, Peter R. Schreiner, Dirk Trauner,
and Wesley D. Allen
Chem. Eur. J.
2014
,
20
, 1638–1645.
DOI: 10.1002/chem.201303081
Now working at
Macromolecular Science and Technology
Aberdeen Proving Ground
Maryland 21005, USA
Former graduate Student, Research Associate
Field of Work
Synthesis and investigation of hexaphenylethane derivatives in terms of reactivity, stability, and intramolecular interactions.
Now:
Process Chemist
Patheon, by Thermo Fisher Scientific
Patheon Austria GmbH & Co KG
St.-Peter-Strasse 25
4020 Linz, Austria
soeren.roesel@thermofisher.com
Photo: Katrina Friese
Publications
London Dispersion Enables the Shortest Intermolecular Hydrocarbon H...H Contact.
Sören Rösel
,
Henrik Quanz
,
Christian Logemann
,
Jonathan Becker
,
Estelle Mossou
,
Laura Cañadillas-Delgado
,
Eike Caldeweyher
,
Stefan Grimme
and
Peter R. Schreiner.
J. Am. Chem. Soc.
2017
,
139 (22)
, 7428-7431.
DOI: 10.1021/jacs.7b01879
Sizing the Role of London dispersion in the Dissociation of all-meta tert-butyl Hexaphenylethane.
Sören Rösel, Ciro Balestrieri and Peter R. Schreiner.
Chem. Sci.
2017
,
8 (1)
, 405-410.
DOI:
10.1039/C6SC02727J
Graduate Student, Research Associate, Scientific Secretary SPP 1807
Field of Work
Dispersion Interactions in Catalysis
Publications
Hexaphenylditetrels – When Longer Bonds Provide Higher Stability
Lars Rummel, Jan M. Schümann, and Peter R. Schreiner
Chem. Eur. J . 2021, 27, 13699 - 13702. DOI: 10.1002/chem.202102271
Gauging the Steric Effects of Silyl Groups with a Molecular Balance
Henrik F. König, Lars Rummel, Heike Hausmann, Jonathan Becker, Jan M. Schümann, and Peter R. Schreiner
J. Org. Chem . 2022, 87, 7, 4670 - 4679. DOI: 10.1021/acs.joc.1c03103
London Dispersion Favors Sterically Hindered Diarylthiourea Conformers in Solution
Lars Rummel, Marvin H. J. Domanski, Heike Hausmann, Jonathan Becker, and Peter R. Schreiner
Angew. Chem. Int. Ed . 2022, 61, e202204393. DOI: 10.1002/anie.202204393
London Dispersion Stabilizes Chloro-Substituted cis -Double Bonds
Lars Rummel, Kai Hanke, Jonathan Becker, and Peter R. Schreiner
Synlett , 2022, Accepted Manuscript, DOI: 10.1055/a-1928-2473
Silyl Groups are Strong Dispersion Energy Donors
Lars Rummel , Henrik F. König, Heike Hausmann, and Peter R. Schreiner
J. Org. Chem . 2022, 87, 19, 13168 - 13177. DOI: 10.1021/acs.joc.2c01633
Research Associate, Kekulé-Fellow
Field of Work
Machine Learning, Graph Representations, Computational Chemistry , Data Science, Molecular Catalysis
Publications
- M. Ruth , D. Gerbig, P. R. Schreiner, A Machine Learning Approach for Bridging the Gap between Density Functional Theory and Coupled Cluster Energies, J. Chem. Theory Comput. 2023 , 19, 15, 4912–4920.
- M. Ruth , D. Gerbig, P. R. Schreiner, Machine Learning of Coupled Cluster (T)-Energy Corrections via Delta (Δ)-Learning, J. Chem. Theory Comput. 2022 , 18 , 8 , 4846–4855 .
- E. Solel , M. Ruth, P. R. Schreiner, London Dispersion Helps Refine Steric A-Values: Dispersion Energy Donor Scales, J. Am. Chem. Soc . 2021 , 143 , 49, 20837–20848.
- B. Bernhardt , M. Ruth , H. P. Reisenauer, P. R. Schreiner, Aminohydroxymethylene (H 2 N–C̈–OH), the Simplest Aminooxycarbene, J. Phys. Chem. A 2021 , 125 , 32, 7023–7028.
- E. Solel , M. Ruth, P. R. Schreiner, London Dispersion Helps Refine Steric A-Values: The Halogens, J. Org. Chem . 2021 , 86 , 11, 7701–7713.
- B. Bernhardt , M. Ruth, A. K. Eckhardt, P. R. Schreiner, Ethynylhydroxycarbene (H–C≡C–C̈–OH), J. Am. Chem. Soc . 2021 , 143 , 10, 3741–3746.
Teaching
- Chemie-BK14 / BLC-13 Organische Chemie 2 - Reaktionsmechanismen
- 07-BDS-10 / 07-NDS-04 Ringvorlesung Data Science (Molecular Machine Learning)
General Research Interest
- Machine Learning / Artificial Intelligence
- Computational Chemistry
- Organocatalysis
- Quantum Mechanical Tunneling
- Matrix Isolation
Graduate Student, Research Associate
Field of Work
Reactive intermediates , (low-temperature) NMR-spectroscopy, Matrix isolation spectroscopy of reactive intermediates, Computational chemistry
Now:
Photo: Katrina Friese
Graduate Student, former Research Associate, Scientific Secretary SPP 1807
Field of Work
SPP 1807 - Control of London dispersion interactions in molecular chemistry
Photo: Katrina Friese
Research Associate
Arbeitsgebiete / Areas of research:
Funktionalisierung von Diamantoiden / Functionalization of diamondoids
Publikationen / Publications:
[1] 2,2,2-Trifluoroethanol: An Unusual Solvent and Valuable Reagent. Hartmut Schwertfeger Synlett Spotlight , 2010 , accepted for publication.
[2] Diamantoide – Chemie mit Nano-Juwelen. Hartmut Schwertfeger, Peter R. Schreiner Chem. Unserer Zeit , 2010 , accepted for publication.
[4] Synthesis of Diamondoid Nitro Compounds from Amines with m -Chloroperbenzoic Acid. Functionalized Nanodiamonds, part 27. Hartmut Schwertfeger, Christian Würtele and Peter R. Schreiner* Synlett 2010 , 493-495. Download
[5] Selective Preparation of Diamondoid Fluorides. Functionalized Nanodiamonds, part 18. Hartmut Schwertfeger, Christian Würtele, Heike Hausmann, Jeremy E. P. Dahl, Robert M. K. Carlson, Andrey A. Fokin and Peter R. Schreiner* Adv. Synth. Catal. 2009 , 351 , 1041-1054. Download
[6] Synthesis of Diamantane Derived N-Heterocyclic Carbenes (IDAd) and Applications in Catalysis. Functionalized Nanodiamonds, part 13. Heinrich Richter, Hartmut Schwertfeger, Peter R. Schreiner,* Roland Fröhlich, and Frank Glorius* Synlett 2009 , 193-197. Download
[7] Synthetic Routes to Aminotriamantanes, Topological Analogues of the Neuroprotector Memantine. Functionalized Nanodiamonds, part 11. Andrey A. Fokin,* Anika Merz, Natalie A. Fokina, Hartmut Schwertfeger, Shenggao L. Liu, Jeremy E. P. Dahl, Robert M. K. Carlson, and Peter R. Schreiner* Synthesis 2009 , 909 – 912. Download
[8] Monoprotection of Diols as a Key Step for the Selective Synthesis of Unequally Disubstituted Diamondoids (Nanodiamonds). Functionalized Nanodiamonds, part 10. Hartmut Schwertfeger, Christian Würtele, Michael Serafin, Heike Hausmann, Robert M. K. Carlson, Jeremy E. P. Dahl, and Peter R. Schreiner* J. Org. Chem. 2008 , 73 , 7789 – 7792. Highlight: Monoprotection of Diamondoid Diols. Timothy M. Swager, Eric L. Dane Synfacts 2008 , 1275. Download
[9] Diamonds are a chemist’s best friend: Diamondoid chemistry beyond adamantane (Functionalized Nanodiamonds, part 7). Hartmut Schwertfeger, Andrey A. Fokin,* and Peter R. Schreiner* invited review for Angew. Chem. Int. Ed. 2008 , 47 , 1022 – 1036. Listed as one of the most accessed articles 01/2008. Download
[10] Diamantoide - Winzige Diamanten aus Erdöl. Hartmut Schwertfeger und Peter R. Schreiner* in Hessen-Nanotech News 2008 , 6 , 14. Download
[11] Kleine Diamanten ganz groß – Diamantoide als neuartige Materialien. Hartmut Schwertfeger und Peter R. Schreiner* in Industrie Diamanten Rundschau 2007 , IV, 50-53. Download
[12] Chemische Triebkräfte – Von der Verbrennung bis zum Herzschlag. Jürgen Janek, Albert Seibert, Jan Philipp Hofmann, Hartmut Schwertfeger, Chem. Unserer Zeit 2004 , 38 , 10-23. Download
Patentanmeldungen / Patent applications:
[1] Monoveretherte Diole der Diamantoide, WO 2009/147141 A2 & DE 10 2008 027 341 A1
[2] Monoether-Derivate von Diolen, deren OH-Gruppen sich in 2-Stellung zu Kohlenstoffatomen mit π-Elektronenpaaren befinden, WO 2009/147145 A1 & DE 10 2008 027 334 A1
Graduate Student, former Research Associate
|
Field of Work:
Kinetic resolution using peptide-based catalysts
|
Photo: Katrina Friese
Graduate Student, Research Associate, Coordinator Liebig College
Field of Work
Design of new Photoswitchable Catalysts, Photoswitchable (Organo-)catalysis, Site-Selective catalysis, Organocatalysis
|
Now:
|
|
Universität Tübingen
Institut für Organische Chemie
philipp.wagner@orgchem.uni-tuebingen.de
|
Photo: Katrina Friese
Graduate Student, Research Associate
Field of Work
„Substitutionsmaterialien für nachhaltige Energietechnologien“
„Substitute Materials for Sustainable Energy Technologies“
London Dispersion Interactions , Hydrocarbon Synthesis, Organic Materials
Research Associate, Scientific Aide
|
Field of Work
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